Thermal Expansion of Single-Crystal H2O and D2O Ice Ih

Autor:	S. H. Masunaga, David T. W. Buckingham, Yi-Kuo Yu, John J. Neumeier
Rok vydání:	2018
Předmět:	Physics Phonon General Physics and Astronomy Ice Ih 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Thermal expansion Crystallography Lattice (order) 0103 physical sciences Kinetic isotope effect 010306 general physics 0210 nano-technology Single crystal
Zdroj:	Physical Review Letters. 121
ISSN:	1079-7114 0031-9007
DOI:	10.1103/physrevlett.121.185505
Popis:	Thermal expansion of ${\mathrm{H}}_{2}\mathrm{O}$ and ${\mathrm{D}}_{2}\mathrm{O}$ ice Ih with relative resolution of 1 ppb is reported. A large transition in the thermal expansion coefficient at 101 K in ${\mathrm{H}}_{2}\mathrm{O}$ moves to 125 K in ${\mathrm{D}}_{2}\mathrm{O}$, revealing one of the largest-known isotope effects. Rotational oscillatory modes that couple poorly to phonons, i.e., lattice solitons, may be responsible.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::677e552460992fb19bdc55e58442fe53 https://doi.org/10.1103/physrevlett.121.185505 Zobrazit plný text záznamu