Internal conversion in highly excited benzene and benzene dimer: femtosecond time-resolved photoelectron spectroscopy

Autor:	C. Dedonder-Lardeux, Th. Freudenberg, V. Stert, Ingolf V. Hertel, W. Radloff, D. Solgadi, Christophe Jouvet
Rok vydání:	1997
Předmět:	Chemistry Dimer General Physics and Astronomy Laser Ion law.invention chemistry.chemical_compound Internal conversion X-ray photoelectron spectroscopy law Excited state Femtosecond Physics::Atomic and Molecular Clusters Molecule Physical and Theoretical Chemistry Atomic physics
Zdroj:	Chemical Physics Letters. 281:20-26
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(97)01142-1
Popis:	Photoelectron spectra of benzene molecules and dimers excited to the S2 electronic state by 140 fs laser pulses at a wavelength of 200 nm have been measured by combining the pump–probe technique with the coincidence detection of ions and electrons. Their time dependence allows one to directly follow the evolution of internal conversion processes in different electronic states on a fs time-scale. Analysis of the corresponding electron energy distribution reveals large variations in the geometry of the different electronic states in both benzene and in its dimer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::67504728c8f7ab1b144c4ffa43012b4f https://doi.org/10.1016/s0009-2614(97)01142-1 Zobrazit plný text záznamu Full Text from ScienceDirect