Hydrocarbon C−H Bond Activation by a Tungsten Acetylene Complex

Autor:	Sean A. Lumb, Peter Legzdins, F. W. B. Einstein, Raymond J. Batchelor, Jeff D. Debad, Steven J. Rettig
Rok vydání:	1999
Předmět:	Inorganic Chemistry Solvent chemistry.chemical_classification chemistry.chemical_compound Hydrocarbon C h bond Acetylene chemistry Organic Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Tungsten Photochemistry
Zdroj:	Organometallics. 18:3414-3428
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om9904450
Popis:	Thermal activation of Cp*W(NO)(η2-CPhCH2)(CH2SiMe3) (1) in neat hydrocarbon solutions transiently generates Cp*W(NO)(η2-PhC⋮CH) (A), which subsequently activates solvent C−H bonds. For example, the...
Databáze:	OpenAIRE
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