Thermodynamics of triple alternating copolymer ethylene—carbon monoxide—propylene

Autor:	L. Ya. Tsvetkova, T. G. Kulagina, O. N. Golodkov, M. S. Kozlova, Yu. A. Zakharova, A. V. Markin, N. N. Smirnova, G. P. Belov
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Chemistry Propane Phase (matter) Thermodynamics General Chemistry Thermodynamic databases for pure substances Calorimetry Combustion Heat capacity Standard enthalpy of formation Calorimeter
Zdroj:	Russian Chemical Bulletin. 63:621-626
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-014-0483-0
Popis:	The temperature dependence of heat capacity of triple alternating copolymer ethylene—carbon monoxide—propylene with 23.4 mol.% of propane fragments was studied for the first time by adiabatic and dynamic calorimetry over the range of 6–480 K. The energy of copolymer combustion at 298.15 K was measured in isothermic calorimeter with stationary bomb. The thermodynamic parameters of phase and physical transitions were determined. The standard thermodynamic functions Cp○(T), H○(T) − H○(0), S○(T) − S○(0) and G○(T) − H○(0), for region from T→ 0 to 320 K, the standard enthalpy of combustion and thermodynamic characteristics of formation of the studied compound at 298.15 K were calculated from the experimental data. The thermodynamic parameters of alternating copolymerization of CO with ethylene and propylene at standard pressure over 0–300 K region were detemined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::673c1a44883f381955815b766534bbf0 https://doi.org/10.1007/s11172-014-0483-0 Zobrazit plný text záznamu Full text from SpringerLink