Lanthanide(III) complexes of six-nitrogen-donor macrocyclic ligands with benzyl-type peripheral substituents, and crystal structure of [La(NO3)2(H2O)(C36H38N6)](NO3)(H2O)

Autor:	Kristine M. Samaria, Adedoyı́n M. Adeyga, Gabriella Bombieri, Lidia M. Vallarino, Kathleen K. Fonda, Franco Benetollo, William A. Gootee
Rok vydání:	2002
Předmět:	Lanthanide Chemistry Stereochemistry chemistry.chemical_element Crystal structure Nitrogen Inorganic Chemistry Crystallography Materials Chemistry Structural isomer Side chain Proton NMR Molecule Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 21:425-433
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(01)01008-7
Popis:	Lanthanide(III) complexes of six-nitrogen-donor macrocyclic ligands carrying a benzyl-type group, CH2C6H4X (X=H, OH, or NH2), at each di-imine side chain were synthesized by the metal-templated, cyclic Schiff-base condensation of 2,6-diacetylpyridine with substituted S- or R,S-1,2-diaminopropanes. The complexes were obtained as mixtures of constitutional isomers and stereoisomers, which were identified by 1H NMR spectra and separated by fractional crystallization. The molecular structure of the 11-coordinate complex [La(NO3)2(H2O)(C36H38N6)](NO3)(H2O) was established by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6739d4d6d1486a0c9434415686543901 https://doi.org/10.1016/s0277-5387(01)01008-7 Zobrazit plný text záznamu Full Text from ScienceDirect