Synthesis and chiroptical properties of axially chiral, binaphthol-based oligomers

Autor:	Thomas C. W. Mak, Hak-Fun Chow, Man-Kit Ng, Tze-Lock Chan
Rok vydání:	1996
Předmět:	genetic structures Chemistry Organic Chemistry Optically active Photochemistry Biochemistry eye diseases Crystallography chemistry.chemical_compound Monomer Tetramer Drug Discovery Optical rotation Axial symmetry
Zdroj:	Tetrahedron Letters. 37:2979-2982
ISSN:	0040-4039
DOI:	10.1016/0040-4039(96)00478-9
Popis:	Optically active, axially chiral binaphthol-based oligomers 2 to 4 were synthesized via Hay's coupling from the monomer 1 . These oligomers exhibited moderate optical rotation enhancement but the effect quickly reaches a plateau with the tetramer 4 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6736cd81e3bc55736e8e6f9e3cca479d https://doi.org/10.1016/0040-4039(96)00478-9 Zobrazit plný text záznamu Full Text from ScienceDirect