Synthesis of hydroxydihydroeremophilone
| Autor: | A. Reginald Pinder, W. Daniel Saunders |
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| Rok vydání: | 1978 |
| Předmět: | |
| Zdroj: | Journal of the Chemical Society, Perkin Transactions 1. :282 |
| ISSN: | 1364-5463 0300-922X |
| DOI: | 10.1039/p19780000282 |
| Popis: | Hydroxydihydroeremophilone (HDE) has been synthesized from eremophilone by two procedures. In one the kinetic enolate of 1,10-dihydroeremophilone was oxidised with molybdenum peroxide to the 8β-epimeride of HDE, which was then epimerised by acid to HDE. Alternatively the trimethylsilyl ether of the kinetic enolate could be oxidised by peracid to an α-trimethylsilyloxyketone, which was then hydrolysed by acid to HDE. |
| Databáze: | OpenAIRE |
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