Treatment of thermoplastic rubberwith chlorine bleach as an alternative halogenation treatment in the footwear industry
| Autor: | P. Gottschalk, Carmen M. Cepeda-Jiménez, J.M. Martín-Martínez, M. Mercedes Pastor-Blas |
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| Rok vydání: | 2003 |
| Předmět: |
chemistry.chemical_classification
Materials science Thermoplastic Bleach Halogenation chemistry.chemical_element Surfaces and Interfaces General Chemistry Surfaces Coatings and Films Styrene chemistry.chemical_compound Natural rubber chemistry Mechanics of Materials visual_art Materials Chemistry visual_art.visual_art_medium Chlorine Adhesive Trichloroisocyanuric acid Composite material |
| Zdroj: | The Journal of Adhesion. 79:207-237 |
| ISSN: | 1545-5823 0021-8464 |
| Popis: | Avoidance of solvents in bonding operations is a current demand in the footwear industry. Halogenation of rubber soles with solutions of trichloroisocyanuric acid (TCI) in different solvents has been successfully used to improve bonding to the leather uppers. In this study, the use of chlorine bleach as an alternative water surface treatment for a rubber has been tested. A thermoplastic block styrene thermoplastic (TR) was treated with bleach to improve its adhesion to a water-based polyurethane dispersion adhesive (PUD). T-peel testing, scanning electron microscopy (SEM), contact angle measurements (ethanediol, 25°C), and infrared spectroscopy (ATR-IR) were used to analyze the modifications produced on the rubber surface. Adhesion values were obtained from T-peel testing of joints produced with similarly treated TR rubber test pieces. Different experimental variables were considered in this study, namely the immersion time (0.5-2 min) in bleach, the active chlorine content (43.9- 55.6 g/l) in the bleach,... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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