Acetylen-Komplexe von Di(η5-cyclopentadienyl)molybdän: Synthesen und Protonierung. Struktur von [Cp2MoH{η2-C2(SiMe3)2}]PF6

Autor:	W. Faßbender, G.E. Herberich, U. Englert
Rok vydání:	1991
Předmět:	Stereochemistry Organic Chemistry Protonation Crystal structure Biochemistry Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Acetylene X-ray crystallography Materials Chemistry Molecule Physical and Theoretical Chemistry Cyclic voltammetry Methyl acrylate Metallocene
Zdroj:	Journal of Organometallic Chemistry. 420:303-314
ISSN:	0022-328X
DOI:	10.1016/0022-328x(91)86457-2
Popis:	Cp2MoH2 reacts with methyl acrylate in the presence of acetylenes (L = C2H2, C2Me2, HCCtBu, HCCSiMe3, C2(SiMe3)2, HCCCH2OMe, HCCCH2NMe2) to form acetylene complexes Cp2Mo(L) 5. Protonation takes place with CF3CO2H at −80°C to give short-lived cations [Cp2MoH(L)+ (8) (L = C2Me2, HCCSiMe3, C2(SiMe3)2). The structure of [Cp2MoH{η2-C2(SiMe3)2}]PF6(9) was determined by an X-ray diffraction study.
Databáze:	OpenAIRE
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