Selective Buchwald–Hartwig arylation of C-amino-1,2,4-triazoles and other coordinating aminoheterocycles enabled by bulky NHC ligands and TPEDO activator
Autor: | Alexander V. Astakhov, Andrey Yu. Chernenko, Vadim V. Kutyrev, Gleb S. Ranny, Mikhail E. Minyaev, Victor M. Chernyshev, Valentine P. Ananikov |
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Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Inorganic Chemistry Frontiers. 10:218-239 |
ISSN: | 2052-1553 |
Popis: | A facile method for selective N-(hetero)arylation of coordinating 3(5)-amino-1,2,4-triazoles under Pd/NHC catalysis using TPEDO as a new efficient Pd(ii) to Pd(0) reductant has been developed. |
Databáze: | OpenAIRE |
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