Crystal and molecular structure of the [Y(Phen){(i-C4H9)2PS2}2NO3] mixed-ligand compound

Autor:	R. F. Klevtsova, S. V. Larionov, V. L. Varand, L. A. Glinskaya
Rok vydání:	2008
Předmět:	Inorganic Chemistry Crystal Dodecahedron Crystallography Molecular geometry Chemistry Coordination number Materials Chemistry Molecule Orthorhombic crystal system Crystal structure Physical and Theoretical Chemistry Diffractometer
Zdroj:	Journal of Structural Chemistry. 49:175-180
ISSN:	1573-8779 0022-4766
DOI:	10.1007/s10947-008-0025-4
Popis:	The [Y(Phen){(i-C4H9)2PS2}2NO3] mixed-ligand compound (I) was synthesized. Its structure was determined by X-ray diffraction analysis (X8 APEX diffractometer, λMoK α , 3788 F hkl , R = 0.0677). Crystals I are orthorhombic: a = 10.6495(8) A, b = 20.006(2) A, c = 35.317(4) A, V = 7524.4(13) A3, Z = 8, ρcalc = 1.324 g/cm3, space group Pbca. The structure is built of mononuclear discrete molecules. The N2O2S4 coordination polyhedron of the Y atom is a distorted dodecahedron.
Databáze:	OpenAIRE
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