Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate

Autor:	Takeshi Shimizu, Tadashi Nakata, Sayoko Hiranuma
Rok vydání:	1996
Předmět:	Chemistry Group (periodic table) Caesium Organic Chemistry Drug Discovery Leaving group chemistry.chemical_element Physical chemistry Biochemistry Inversion (discrete mathematics)
Zdroj:	Tetrahedron Letters. 37:6145-6148
ISSN:	0040-4039
Popis:	Inversion of a variety of secondary alcohols using the (chloromethylsulfonyl)oxy group as a favorable leaving group with cesium acetate in the presence of 18-crown-6 has been performed to give the inverted acetates in high yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66f5074ea087076be0718af5eb0c5717 https://doi.org/10.1016/0040-4039(96)01333-0 Zobrazit plný text záznamu Full Text from ScienceDirect