Gas-liquid chromatographic separation and spectrometric identification of nitrogen bases in hydrocracked shale oil naphtha

Autor:	F. R. McDonald, H. B. Jensen, Dennis. Brown, D. G. Earnshaw
Rok vydání:	1970
Předmět:	Chromatography Chemistry Mass spectrometry Analytical Chemistry law.invention Synthetic fuel law Shale oil Mass spectrum Organic chemistry Gas chromatography Energy source Distillation Naphtha
Zdroj:	Analytical Chemistry. 42:146-151
ISSN:	1520-6882 0003-2700
DOI:	10.1021/ac60284a007
Popis:	A tar-base concentrate from a hydrocracked shale oil naphtha was separated by gas-liquid partition chromatography using nonpolar and polar columns. Final cuts were analyzed by mass, infrared, and nuclear magnetic resonance spectrometry. Fifty individual compounds were identified and eight additional structures are proposed as possible components of the concentrate. Alkylpyridines comprised about 64% of the bases and alkylanilines about 33%; the rest of the bases were quinoline and small quantities of cycloalkanopyridines. Substitution patterns for both the alkylpyridines and alkylanilines showed that a substitution was favored over B or Y, and Y was favored over B.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66d7e4a171ccdb6c3d61061d76a4bce4 https://doi.org/10.1021/ac60284a007 Zobrazit plný text záznamu