Pentafluorosulfanyl (SF 5 ) Containing Energetic Salts

Autor:	Michael E. Sitzmann, Jean'ne M. Shreeve, Rolf W. Winter, Chengfeng Ye, Haixiang Gao, Gary L. Gard
Rok vydání:	2006
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Pyridine Ionic liquid Inorganic chemistry Melting point Standard enthalpy change of formation Standard enthalpy of formation
Zdroj:	European Journal of Inorganic Chemistry. 2006:3221-3226
ISSN:	1099-0682 1434-1948
Popis:	New quaternary salts of pentafluorosulfanyl-substituted (SF5) N-methylimidazole (1), 4-amino-1,2,4-triazole (3) or pyridine (5) were prepared and characterized. Most of the salts exhibit good thermal stabilities and low melting points placing them in the ionic liquid class. Their densities range between 1.4 and 1.8 g/cm3. The standard enthalpies of formation for the new salts were calculated by the use of computationally feasible DFT(B3LYP) and MP2 methods in conjunction with an empirical approach based on densities of salts. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
Databáze:	OpenAIRE
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