Upgrading of Scenedesmus obliquus oil to high-quality liquid-phase biofuel by nickel-impregnated biochar catalyst
| Autor: | Alexander L. Ido, Dennis C. Ong, Mark Daniel G. de Luna, Sergio C. Capareda |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Central composite design Renewable Energy Sustainability and the Environment 020209 energy Strategy and Management 05 social sciences 02 engineering and technology Pulp and paper industry Industrial and Manufacturing Engineering chemistry.chemical_compound Diesel fuel chemistry Biofuel Yield (chemistry) Biochar 050501 criminology 0202 electrical engineering electronic engineering information engineering Heat of combustion Response surface methodology Fatty acid methyl ester 0505 law General Environmental Science |
| Zdroj: | Journal of Cleaner Production. 209:1052-1060 |
| ISSN: | 0959-6526 |
| DOI: | 10.1016/j.jclepro.2018.10.028 |
| Popis: | This work investigated the optimization of process parameters in the upgrading of the oil extracted from Scenedesmus obliquus microalgae using a novel nickel-impregnated biochar catalyst. The effects of temperature, dodecane-to-oil mass ratio and pressure on the upgraded liquid-phase biofuel yield were evaluated and optimized by central composite design of the response surface methodology (RSM). The model equation generated from RSM showed that dodecane-to-oil mass ratio and pressure, as well as the quadratic effects of all the three factors, were significant model terms in predicting the yield of upgraded liquid-phase biofuel. Maximum liquid biofuel yield was attained at 246.89 °C, 3.72 (w/w) dodecane-to-oil mass ratio, 3.84 MPa hydrogen pressure and 6 h processing time. Validation runs resulted in an upgraded biofuel yield of 69.4%, which was in close agreement with predicted values generated by RSM. The upgraded biofuel comprised of 100% green liquid hydrocarbons containing 94% alkanes and 6% alkenes. Its main fuel properties, such as heating value (43.78 MJ kg−1), elemental composition, density, and viscosity, exceeded those of the fatty acid methyl ester standard and were found comparable to those of petroleum diesel. More importantly, the results of the ultimate analysis and confirmed by the findings from Fourier transform infrared and gas chromatography – mass spectroscopy analyses, showed significantly low oxygen and nitrogen content and absence of sulfur in the upgraded biofuel. |
| Databáze: | OpenAIRE |
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