Aliphatic bromination with tetrabromomethane on immobilized copper complexes

Autor:	Alexey K. Buryak, V. M. Zelikman, Irina Tarkhanova
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Bromine chemistry Process Chemistry and Technology Yield (chemistry) Tetrabromomethane chemistry.chemical_element Halogenation Physical and Theoretical Chemistry Photochemistry Copper Catalysis
Zdroj:	Journal of Molecular Catalysis A: Chemical. 407:60-66
ISSN:	1381-1169
Popis:	New catalytic systems with supported bromine- and chlorine-containing copper complexes for selective bromination of alkanes with tetrabromomethane have been proposed. Introduction of donor additives (e.g., low-molecular-weight alcohols) into the reaction increases the activity and stability of these catalysts. The kinetic features of the processes have been investigated. It has been shown that the dependences of the yield of bromodecanes on temperature and concentration of donor additives are both nonmonotonic in character.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66c3d7c1077bd827d93812d3de2c1937 https://doi.org/10.1016/j.molcata.2015.06.022 Zobrazit plný text záznamu Full Text from ScienceDirect