Plutonium Oxide Polishing for MOX Fuel Production

Autor: Elizabeth A. Bluhm, Simon Balkey, Yvonne A. Martinez, Daniel J. Garcia, Brenda J. Griego, Benjie T. Martinez, Carl D. Martinez, Manuelita M. Valdez, Judy D. Roybal, David Martinez, James T. Dyke, Jason Brock, Joe Ray Martinez, Jose A. Valdez, Kent D. Abney, Fawn Coriz, Brian K. Bluhm, Lonny Morgan, Kevin B. Ramsey
Rok vydání: 2005
Předmět:
Zdroj: Separation Science and Technology. 40:281-296
ISSN: 1520-5754
0149-6395
Popis: Los Alamos National Laboratory (LANL) has been tasked to produce 120 kg of plutonium as highly purified PuO2 for the European Mixed Oxide (MOX) Lead Test Assembly managed by Duke, COGEMA, Stone & Webster (DCS). To meet stringent and challenging technical requirements for PuO2 production, the LANL aqueous polishing team recently established consistency in generating quality material from weapons‐grade PuO2. Polishing was required to remove undesirable quantities of trace‐metal impurities, particularly gallium, and to produce a material with appropriate powder characteristics, such as particle size and surface area. The process flow sheet for PuO2 polishing was based on aqueous purification and included the unit operations of dissolution, ion exchange, oxalate precipitation, and calcination. This article is not subject to U.S. copyright law. Funding was provided by the LANL Fissile Materials Disposition Program (NN60). Los Alamos National Laboratory is operated by the University of California under...
Databáze: OpenAIRE