Primary and Secondary Ferrocenylphosphine Complexes of Molybdenum(II) and Tungsten(II), [MI2(CO)3-n(PH2R)2+n] [M = Mo, W; R = Fc, FcCH2; Fc = Fe(η5-C5H5)(η5-C5H4); n = 0, 1], [MI2(CO)3{PH(CH2Fc)2}2], and [WI2(CO)3(NCMe){PH(CH2Fc)2}]: Preparation, Molecular Structure, Dynamic Behavior, Catalytic Properties, and Theoretical Calculations

Autor:	René Sommer, Peter Lönnecke, Joachim Reinhold, Paul K. Baker, Evamarie Hey-Hawkins
Rok vydání:	2005
Předmět:	Inorganic Chemistry Primary (chemistry) chemistry Molybdenum Organic Chemistry Inorganic chemistry chemistry.chemical_element Molecule Physical and Theoretical Chemistry Tungsten Medicinal chemistry Catalysis
Zdroj:	Organometallics. 24:5256-5266
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om0501982
Popis:	Reaction of [MI2(CO)3(NCMe)2] [M = Mo, W] with 2 or 3 equiv of PH2Fc or PH2CH2Fc [Fc = Fe(η5-C5H5)(η5-C5H4)] in CH2Cl2 or THF at various temperatures gave [MI2(CO)3L2] [M = Mo: L = PH2Fc (1a), PH2...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66aece3b14b267cb28247fd907144860 https://doi.org/10.1021/om0501982 Zobrazit plný text záznamu