Synthesis and characterization of La0.7Sr0.3Mn1−x TixO3 manganites
| Autor: | Alexandr Tovstolytkin, O. Z. Yanchevskiĭ, Oleg V'yunov, Anatolii Belous, V. P. Kravchik |
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| Rok vydání: | 2006 |
| Předmět: |
Materials science
Solid-state physics chemistry.chemical_element Manganese Condensed Matter Physics Oxygen Ferromagnetic resonance Spectral line Electronic Optical and Magnetic Materials Crystallography Nuclear magnetic resonance chemistry Ferromagnetism Electrical resistivity and conductivity Titanium |
| Zdroj: | Physics of the Solid State. 48:709-716 |
| ISSN: | 1090-6460 1063-7834 |
| DOI: | 10.1134/s1063783406040159 |
| Popis: | The structural, electrical and magnetic properties of the La0.7Sr0.3Mn1−x TixO3 system characterized by rhombohedral lattice distortions are studied. Substitution of titanium for manganese weakens ferromagnetism and leads to an increased resistivity. Using x-ray Rietveld full-profile refinement data and ferromagnetic resonance spectra, it is demonstrated that titanium substitution for manganese occurs with charge compensation according to the equation Mn4+ → Ti4+ and with a simultaneous decrease in the oxygen nonstoichiometry as the value of x increases. |
| Databáze: | OpenAIRE |
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