Catalytic B(C6F5)3H2O-promoted defluorinative functionalization of tertiary aliphatic fluorides
| Autor: | Guang Li, Marian Dryzhakov, Joseph Moran, Edward Richmond |
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| Rok vydání: | 2017 |
| Předmět: |
Reaction conditions
010405 organic chemistry Chemistry Organic Chemistry Carbocation 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound Thioether Environmental Chemistry Surface modification Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Brønsted–Lowry acid–base theory |
| Zdroj: | Journal of Fluorine Chemistry. 193:45-51 |
| ISSN: | 0022-1139 |
| Popis: | A B(C 6 F 5 ) 3 H 2 O-catalyzed defluorinative functionalization of tertiary aliphatic fluorides is described that proceeds under benign reaction conditions. The synthetic utility of the method is exemplified through the fast and efficient formation of a range of products with newly installed C(sp 3 ) N, S, C and O bonds. This study illustrates the broad reactivity of otherwise inert starting materials and provides a route to valuable and synthetically underrepresented products that have not been accessed previously from such fluorinated precursors. |
| Databáze: | OpenAIRE |
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