Medium temperature operation of fuel cells using thermally stable proton-conducting composite sheets composed of phosphosilicate gel and polyimide
| Autor: | Tsutomu Minami, Naoki Nakamoto, Masahiro Tatsumisago, Atsunori Matsuda, Kiyoharu Tadanaga |
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| Rok vydání: | 2004 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Vapour pressure of water Composite number Membrane electrode assembly Energy Engineering and Power Technology Electrolyte Conductivity Chemical engineering Electrode Relative humidity Electrical and Electronic Engineering Physical and Theoretical Chemistry Polyimide |
| Zdroj: | Journal of Power Sources. 138:51-55 |
| ISSN: | 0378-7753 |
| Popis: | Fuel cells using a composite sheet composed of phosphosilicate (P 2 O 5 -SiO 2 , P/Si = 1 in mole ratio) gel powder and polyimide operated up to 150 °C under a relatively low water vapor pressure. Maximum power density of the fuel cell increased with increasing operation temperature up to 150 °C and increasing humidity. No degradation was observed even after the continuous operation for 10 h at 150 °C and 4% relative humidity (RH) under 50 mA cm −2 . Sieving of the mechanically milled phosphosilicate gel powders to be less than 5 μm in size was found to improve the homogeneity and thus the proton conductivity of the resultant composite sheets. The conductivity of the composite sheet containing 75 wt.% of the sieved gel powder was 4 × 10 −3 S cm −1 at 150 °C and 18% RH. Good contact between the composite sheet as an electrolyte and Pt-loaded carbon paper sheets as electrodes in the membrane electrode assembly (MEA) was very important to attain high performance of the fuel cells, which was achieved by the painting of phosphosilicate sol on the surface of the carbon paper and the hot-pressing of the MEA in vacuo. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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