Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp2 Carbon Cages

Autor: Jianyuan Zhang, Antonio Rodriguez-Fortea, Yanbang Li, William P. Kopcha
Rok vydání: 2022
Předmět:
Zdroj: Synlett. 33:907-912
ISSN: 1437-2096
0936-5214
DOI: 10.1055/a-1741-9000
Popis: We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. This account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu3N@C80.1 Introduction2 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Alkynes3 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Allenes4 Conclusion
Databáze: OpenAIRE