ChemInform Abstract: Reaction of 1,1-Diiododinitroethylene with Fluoride. Preparation of 1, 1,1-Trifluorodinitroethane Derivatives

Autor:	Kurt Baum, N. V. Nguyen, Sean S. Bigelow
Rok vydání:	2010
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Sodium bicarbonate chemistry Trioxane Extraction (chemistry) Ethyl acetate Formaldehyde Salt (chemistry) Sulfuric acid General Medicine Fluoride Nuclear chemistry
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199243129
Popis:	The reaction of 1,1-diiododinitroethylene with tetrabutylammonium fluoride gave the tetrabutylammonium salt of 1,1,1-trifluorodinitroethane. Acidification of this salt in ethyl acetate, extraction of tetrabutylammonium salts with water, and addition of sodium bicarbonate led to the isolation of the sodium salt of 1,1,1-trifluorodinitroethane. The reaction of formaldehyde with the tetrabutylamminium salt gave 3,3,3-trifluoro-2,2-dinitropropanol, which was converted to its formal with trioxane and sulfuric acid.
Databáze:	OpenAIRE
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