Silicon–nitrogen compounds. Part VII. N-silyl derivatives of aniline

Autor:	M. J. Hakim, B. J. Aylett
Rok vydání:	1969
Předmět:	Silicon Hydrogen Silylation Inorganic chemistry chemistry.chemical_element Disproportionation Silane Inorganic Chemistry chemistry.chemical_compound Aniline chemistry Polymer chemistry Lewis acids and bases Physical and Theoretical Chemistry Hydrogen chloride
Zdroj:	J. Chem. Soc. A. :800-803
ISSN:	0022-4944
DOI:	10.1039/j19690000800
Popis:	N-Phenyldisilazane, (SiH3)2NPh, has been prepared from aniline and iodosilane; it is a very weak Lewis base. With less than 1 mol. of hydrogen chloride below –20°, it gives N-phenylsilylamine, SiH3NHPh. In the range 325–380° and at 90° respectively, the new compounds decompose to yield silane and hydrogen. A mechanism involving initial disproportionation about silicon is proposed, and the probable nature of the involatile products is inferred. I.r. and mass spectra are reported and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66054215472a528e44467edb1454bbe4 https://doi.org/10.1039/j19690000800 Zobrazit plný text záznamu