A New Simplified Protocol for Copper(I) Alkyne–Azide Cycloaddition Reactions Using Low Substoichiometric Amounts of Copper(II) Precatalysts in Methanol

Autor:	Amna N. Khan, Harry Heaney, Maria M. P. Figueres, Benjamin R. Buckley
Rok vydání:	2015
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Organic Chemistry Triazole chemistry.chemical_element Alkyne Methanol Azide Copper Combinatorial chemistry Cycloaddition Catalysis
Zdroj:	Synlett. 27:51-56
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0035-1560526
Popis:	Copper(II) carboxylates are reduced efficiently by methanol in the presence of alkynes and form yellow alkynylcopper(I) polymeric precatalysts that are involved with azides, in the absence of added ligands, in the catalytic cycles that result in the formation of 1,4-disubstituted 1,2,3-triazoles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::65f539e858017685734f59db418a651a https://doi.org/10.1055/s-0035-1560526 Zobrazit plný text záznamu