ChemInform Abstract: A Highly Regio- and Stereoselective Selenoxide Elimination of 1,2-Bis[4-(trimethylsilyl)phenylseleno]alkanes to Give (E)-Alkenyl Selenoxides and Its Mechanistic Study

Autor:	Kentaro Yamaguchi, Kenji Arimitsu, Asami Tarao, Aya Niki, Ikuo Kawasaki, Hitomi Uchimoto, Shinsuke Komagawa, Kiyoharu Nishide
Rok vydání:	2016
Předmět:	Elimination reaction Selenoxide elimination chemistry.chemical_compound Trimethylsilyl chemistry Organic chemistry Stereoselectivity General Medicine
Zdroj:	ChemInform. 47
ISSN:	0931-7597
Popis:	Oxidation of organo-selenium compounds (I) with MCPBA generates bisselenoxide intermediates which undergo elimination to give products (II) with high regio- and E/Z-selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::65ef036dfa2352cb6aa5b93bc49edbf8 https://doi.org/10.1002/chin.201626208 Zobrazit plný text záznamu Plný text