Tetracobalt Complexes with Co3 Face-Capping Cycloheptatrienyl and Cyclooctatetraene Ligands

Autor:	Hubert Wadepohl, Stefan Gebert, Fabrizia Grepioni, Dario Braga, Hans Pritzkow
Rok vydání:	1998
Předmět:	Ligand Hydrogen bond Stereochemistry Organic Chemistry Intermolecular force Solid-state chemistry.chemical_element General Chemistry Crystal structure Catalysis Cyclooctatetraene chemistry.chemical_compound Crystallography chemistry Cluster (physics) Cobalt
Zdroj:	Chemistry - A European Journal. 4:279-288
ISSN:	1521-3765 0947-6539
DOI:	10.1002/(sici)1521-3765(19980210)4:2<279::aid-chem279>3.0.co;2-6
Popis:	The novel tetracobalt cluster complexes1 and 2, which contain facial CnHn ligands, have been synthesized and their crystal structures determined. The apical C8H8 ligand can be selectively substituted by a number of other ligands. In the solid state, the hydrogen atoms of the cycloheptatrienyl and cyclooctatetraene ligands take part in intra- and intermolecular hydrogen-bonding interactions of the C−H⋅⋅⋅O type.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::65e985a217c170bfbc277b99bcdba9e8 https://doi.org/10.1002/(sici)1521-3765(19980210)4:2<279::aid-chem279>3.0.co Zobrazit plný text záznamu Plný text