Structural studies of some rhodium(III) acyl complexes containing bidentate phosphines

Autor:	Basu Panthi, Stephen L. Gipson, Andreas Franken
Rok vydání:	2015
Předmět:	Steric effects Denticity Ligand Hydrogen bond Decarbonylation chemistry.chemical_element Medicinal chemistry Square pyramidal molecular geometry Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Acyl group
Zdroj:	Inorganica Chimica Acta. 425:176-181
ISSN:	0020-1693
Popis:	Acyl complexes of rhodium(III) with chelating diphosphine ligands are well known for their stability toward decarbonylation. This stability has allowed us to synthesize and structurally characterize a series of ten related complexes of the type Rh(diphosphine)(COR)I2. All ten display the same square pyramidal geometry with the acyl group in the apical position. The orientation of the acyl ligand is determined by both steric factors and CH⋯O hydrogen bonding between the acyl oxygen and C–H groups on the diphosphine ligand. Results indicate that bis(diphenylphosphino)benzene is significantly more sterically demanding and less electron donating than the bis(diphenylphosphino)propane and bis(diisopropylphosphino)propane ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::65da5f6090b8d57b8bcc0c607b00996e https://doi.org/10.1016/j.ica.2014.09.035 Zobrazit plný text záznamu Full Text from ScienceDirect