Synthesis of substituted titanocene dichloride derivatives by hydrosilylation
| Autor: | Tomáš Strašák, Martin Bernard, Lucie Maixnerová, Lucie Červenková Št’astná, Radek Fajgar, Anna Březinová, Jindřich Karban |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
chemistry.chemical_classification
Double bond Hydrosilylation Organic Chemistry Titanocene dichloride chemistry.chemical_element Standard methods Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Cyclopentadienyl complex Functional group Polymer chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Titanium |
| Zdroj: | Journal of Organometallic Chemistry. 768:115-120 |
| ISSN: | 0022-328X |
| Popis: | Substituted titanocene complexes have been prepared by hydrosilylation of organic substrates containing a terminal double bond by cyclopentadienyl complexes of titanium bearing a Si–H functional group. This new synthetic protocol is demonstrated by synthesis of mono-, bi- and trihomonuclear complexes. The structures of prepared compounds have been characterized by standard methods (NMR, IR, and HRMS). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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