Organotin(IV) chloride complexes of bis-β-ketophosphonium ylides
| Autor: | Ram C. Mehrotra, Raj K. Bansal, Ram Sanehi |
|---|---|
| Rok vydání: | 1986 |
| Předmět: |
Diketone
chemistry.chemical_classification Stereochemistry Organic Chemistry Nuclear magnetic resonance spectroscopy Biochemistry Chloride Medicinal chemistry Adduct Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Ylide Mössbauer spectroscopy Materials Chemistry medicine Molecule Physical and Theoretical Chemistry medicine.drug |
| Zdroj: | Journal of Organometallic Chemistry. 303:351-360 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(86)82037-x |
| Popis: | The coordination behaviour of bis-β-ketophosphonium ylides, (Ph3 P + - C RCO(CH2)nCO C R- P + Ph3) towards some organotin(IV) chlorides has been studied. Accordingly, organotin(IV) chloride complexes of the general formula (Ph3 P + - C RCO(CH2)nCO C R- P + Ph3)R′xSnCl4−x (n = 0 or 2; x= 1−3) have been synthesized and characterized by analysis and IR, 1H, 13C, 31P, 119Sn NMR and Mossbauer spectroscopy. The complexes are 1:1 adducts, containing weak carbon-tin bonds and are non-electrolytes and monomeric in solution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|