Potential Measurements of Reactive Metal Chlorides in Alkali Halide Solutions: II . Chromium

Autor: S. N. Flengas, P. J. Tumidajski
Rok vydání: 1991
Předmět:
Zdroj: Journal of The Electrochemical Society. 138:1659-1665
ISSN: 1945-7111
0013-4651
DOI: 10.1149/1.2085850
Popis: The thermodynamic properties of the dilute solutions of the chromium chlorides were determined in the solvents NaCl, KCl, CsCl, or their equimolar mixtures between approximately 973 and 1173 K using an EMF technique. Galvanic and redox cells with Ag-AgCl reference electrodes were used. The thermodynamic properties imply highly nonideal systems in which the formation of complex species is indicated. A reacting system consisting of Cr metal immersed in a CrCl 3 -KCl solution was studied potentiometrically
Databáze: OpenAIRE