New H-bond accepting tris(pyrazolyl)borates: stabilization of metal aquo species as models for the vicinal oxygen chelate enzyme superfamily

Autor:	Carl J. Carrano, Brian S. Hammes, Mary W. Carrano
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Hydrogen bond Chemistry Ligand Inorganic chemistry General Chemistry Medicinal chemistry Divalent Metal visual_art visual_art.visual_art_medium Chelation Metal aquo complex Vicinal Alkyl
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :1448-1451
ISSN:	1364-5447 1472-7773
DOI:	10.1039/b009621k
Popis:	The hydrogen-bond accepting ligand K[TpCO2Et,Me] was prepared and its complexes with divalent Ni, Co, Mn and Cu reveal a stabilization of penta- or hexa-coordinate metal aquo complexes of the general form [TpCO2Et,MeM(H2O)x] (x = 2 or 3) which are unprecedented for the alkyl substituted Tp analogs. These complexes make good structural models for many of the enzymes of the vicinal oxygen chelate superfamily.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6533bebe6760e708e6e6e2db7d597582 https://doi.org/10.1039/b009621k Zobrazit plný text záznamu