Selective Incorporation of Perfluorinated Phenyl Rings during Pulsed Plasma Polymerization of Perfluoroallylbenzene
| Autor: | Jas Pal Singh Badyal, Alan Michael Hynes |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
Chemistry
General Chemical Engineering Radical polymerization technology industry and agriculture Plasma deposition General Chemistry Photochemistry Plasma polymerization Deposition rate X-ray photoelectron spectroscopy Fragmentation (mass spectrometry) Benzene derivatives Materials Chemistry Organic chemistry Fourier transform infrared spectroscopy |
| Zdroj: | Chemistry of Materials. 10:2177-2182 |
| ISSN: | 1520-5002 0897-4756 |
| Popis: | Pulsed plasma polymerization of perfluoroallylbenzene can lead to the deposition of films containing high concentrations of perfluorinated phenyl groups. X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and deposition rate measurements have shown that low duty cycles give rise to minimal precursor fragmentation accompanied by conventional free radical polymerization during the off-period. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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