A Multifunction Pd/Sc(OTf)3/Ionic Liquid Catalyst System for the Tandem One-Pot Conversion of Phenol to ε-Caprolactam

Autor:	Da Jung Jung, Sang‐gi Lee, Ju Yeon Shin
Rok vydání:	2013
Předmět:	Caprolactam Cyclohexanone oxime Cyclohexanone General Chemistry Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Beckmann rearrangement Ionic liquid Phenol Organic chemistry Selectivity
Zdroj:	ACS Catalysis. 3:525-528
ISSN:	2155-5435
Popis:	A multifunction Pd/Sc(OTf)3/ionic liquid catalyst for the tandem one-pot conversion of phenol to e-caprolactam is reported. Pd and Sc(OTf)3 cooperate to catalyze the hydrogenation of phenol to cyclohexanone with excellent conversion (>99.9%) and selectivity (>99.9%), whereas Sc(OTf)3 and an ionic liquid, [bmim][PF6], cooperate to catalyze the tandem transformation of the resulting cyclohexanone to cyclohexanone oxime and the Beckmann rearrangement affording e-caprolactam.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::65178aaa0f764f1e382ff13e3a9ff029 https://doi.org/10.1021/cs400009w Zobrazit plný text záznamu