Thin film of a porphyrin-end-functionalized poly(cyclohexane)/fullerene-end-functionalized poly(4-diphenylaminostyrene) blend: Control of microphase separation in a light-harvesting system for polymer solar cells
| Autor: | Itaru Natori, Anna Kanasashi, Kosuke Tsuchiya, Kenji Ogino, Shizue Natori |
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| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Materials science Fullerene Polymers and Plastics Cyclohexane General Chemistry Polymer Porphyrin Polymer solar cell Surfaces Coatings and Films chemistry.chemical_compound chemistry Chemical engineering Polymer chemistry Materials Chemistry Polymer blend Thin film Absorption (chemistry) |
| Zdroj: | Journal of Applied Polymer Science. 128:4212-4216 |
| ISSN: | 0021-8995 |
| DOI: | 10.1002/app.38647 |
| Popis: | Thin films of a tetraphenylporphyrin-end-functionalized polycyclohexane zinc complex (ZnTPP-PCHE)/fullerene-C60 (C60) end-functionalized poly(4-diphenylaminostyrene) (C60-PDAS) were prepared to investigate their potential as a light-harvesting system for polymer solar cells (PSCs). The microphase separation in the ZnTPP-PCHE/C60-PDAS blends had a significant effect on the optical properties; the absorption band of the microphase separation structure that overlaps the visible-light region was considerably enhanced with an increase in the C60 concentration in the polymer film, although both pristine ZnTPP-PCHE and C60-PDAS thin films had only weak absorption bands in that region. Therefore, this polymer blend is considered to be suitable for use as a light-harvesting system for PSCs. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| Databáze: | OpenAIRE |
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