Glycerol oxidation by fluorinated and platinized Titania

Autor: E.G. Ávila-Martínez, Julie Joseane Murcia Mesa, J. Cubillos, E. Bautista, O. Cardenas, R. Romero, R. Natividad, María Hidalgo, J.S. Hernández, José Antonio Navío, Ramiro Baeza-Jiménez
Rok vydání: 2021
Předmět:
Zdroj: Ciencia en Desarrollo. 12:135-142
ISSN: 2462-7658
0121-7488
DOI: 10.19053/01217488.v12.n1.2021.12417
Popis: In this work, fluorinated and platinized TiO2 was evaluated in the glycerol oxidation. Fluorination led to increase the specific surface area of titania, and platinization treatment led to obtain the highest absorption in the visible region of the electromagnetic spectrum; thus, 0.5 wt.% Pt-F-TiO2 was the best catalyst in the obtention of highest yield and selectivity to glyceraldehyde (GAL). It was also found that 2wt.% of Pt content had a detrimental effect in the glycerol conversion. Fluorination and platinum addition led to modify the reaction mechanism and selectivity.
Databáze: OpenAIRE