Formation of dications bearing a S(OH)2+ group from long-lived 9,9-dimethyl-10 R-phenanthrenium cations in FSO3H–SbF5/SO2ClF/SO2: a mechanistic study

Autor:	Vyacheslav G. Shubin, V. A. Bushmelev, George E. Salnikov, Alexander M. Genaev, Andrey A. Nefedov
Rok vydání:	2014
Předmět:	Reaction rate Reaction mechanism Chemistry Computational chemistry General Chemical Engineering Protonation General Chemistry Carbon-13 NMR
Zdroj:	RSC Adv.. 4:52831-52835
ISSN:	2046-2069
DOI:	10.1039/c4ra11673a
Popis:	1 H and 13C NMR studies have shown that the long-lived 9,9-dimethyl-10-R-phenanthrenium cations (R = PhCC, Me, OH) generated in FSO3H–SbF5/SO2ClF/SO2/CD2Cl2 transform into long-lived 7-dihydroxysulfonio-9,9-dimethyl-10-R-phenanthrenium dications. The effect of the 10-R substituents on the reaction rate suggests that a key step in the reaction mechanism is addition of SO2 to protonated phenanthrenium cations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::64f145d8ce9531bce544eba343055433 https://doi.org/10.1039/c4ra11673a Zobrazit plný text záznamu