Chiral synthesis of tri-O-methylimbricatine, an etherified derivative of the starfish alkaloid imbricatine

Autor:	Raymond J. Andersen, Masashi Ohba, Masaaki Imasho, Julia Kubanek, Tatsuya Fujii, Yoshikazu Nishimura
Rok vydání:	1998
Předmět:	biology Chemistry Stereochemistry Alkaloid Organic Chemistry Methyl derivative Starfish Dermasterias Enantioselective synthesis biology.organism_classification Biochemistry chemistry.chemical_compound Drug Discovery Derivative (chemistry)
Zdroj:	Tetrahedron Letters. 39:5999-6002
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(98)01232-5
Popis:	A chiral synthesis of tri- O -methylimbricatine ( 2 ), the tri- O -methyl derivative of the unique benzyltetrahydroisoquinoline alkaloid imbricatine ( 1 ) isolated from the starfish Dermasterias imbricata , has been accomplished. As a result of the synthesis, the correctness of the structure and absolute stereochemistry proposed for imbricatine has been unequivocally confirmed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::64dee7f96f95fa2e7d6f559d5ea5f186 https://doi.org/10.1016/s0040-4039(98)01232-5 Zobrazit plný text záznamu Full Text from ScienceDirect