| Autor: | V. I. Vysotskii, V. P. Grigorchuk, M. F. Rostovskaya, T. A. Vysotskaya |
|---|---|
| Rok vydání: | 2001 |
| Předmět: | |
| Zdroj: | Russian Journal of Organic Chemistry. 37:1414-1417 |
| ISSN: | 1070-4280 |
| Popis: | Dehydration of 2-hydroxy-8-R-tricyclo[7.3.1.02,7]tridecan-13-ones (R = H, Me, Ph) effected by various reagents provided 8-R-tricyclo[7.3.1.02,7]tridecen-13-ones with different positions of the double bond. In the presence of phosphoric acid arise isomers with the double bond in 2(3) position, a mixture of hydrochloric and acetic acid primarily affords isomers with the double bond in 2(7) position that further migrates into 7(8) position at R = Me, Ph. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink