Rheokinetics of polymerization of N-laurylmethacrylate
| Autor: | L. T. Kale, K. F. O'Driscoll |
|---|---|
| Rok vydání: | 1982 |
| Předmět: |
Diffraction
chemistry.chemical_classification Materials science Polymers and Plastics Rheometer Radical polymerization technology industry and agriculture macromolecular substances General Chemistry Polymer chemistry.chemical_compound Monomer chemistry Rheology Polymerization Extent of reaction Materials Chemistry sense organs Composite material skin and connective tissue diseases |
| Zdroj: | Polymer Engineering and Science. 22:402-409 |
| ISSN: | 1548-2634 0032-3888 |
| DOI: | 10.1002/pen.760220703 |
| Popis: | The free radical polymerization of n-laurylmethacrylate has been studied using a combination of rheological and kinetic methods. In addition to classical dilatometry, the extent of reaction of a polymerization was followed in a cone and plate rheometer by measuring the change in the diffraction of a laser beam shone through the polymerizing sample parallel to the plate of the rheometer. The change in diffraction was caused by the change in index of refraction of the monomer becoming polymer, which was related to the extent of reaction. Simultaneous measurements of loss and storage moduli and dynamic viscosity at 1 Hz provided the data necessary for correlating changes in the kinetics with changes in the rheology of the polymerizing system. |
| Databáze: | OpenAIRE |
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