Hydroboration of methyl 2-acetamidoacrylate. II — new aspects of the reactivity of the resulting oxytriorganoborates

Autor:	Valérie Denniel, Bertrand Carboni, Renée Danion-Bougot, Patrick Bauchat, Daniel Danion
Rok vydání:	1995
Předmět:	Methyl-2-acetamidoacrylate Hydroboration Nucleophile Chemistry Organic Chemistry Drug Discovery Organic chemistry Reactivity (chemistry) Biochemistry
Zdroj:	Tetrahedron Letters. 36:6875-6878
ISSN:	0040-4039
DOI:	10.1016/0040-4039(95)01398-2
Popis:	The heterocyclic borate complex obtained by hydroboration of methyl 2-acetamidoacrylate acts as an ambident nucleophile, affording N- or C-alkyl or acylalaninates according to experimental conditions. Mechanistic hypotheses are proposed to rationalize these results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::649130780a16183dc3dbf7b189683e44 https://doi.org/10.1016/0040-4039(95)01398-2 Zobrazit plný text záznamu Full Text from ScienceDirect