Simple chemical polymerization method for the deposition of a conducting polyaniline on the surface of acrylonitrile-butadiene-styrene. II. Treatment in organic free solvent
| Autor: | R. J. Martínez Palomino, Vitali Parkhutik, R. Enguix Carrascosa, E. Matveeva |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
Materials science
Polymers and Plastics Acrylonitrile butadiene styrene Cationic polymerization General Chemistry Surfaces Coatings and Films chemistry.chemical_compound Aniline Polybutadiene Polymerization chemistry Pulmonary surfactant Polyaniline Polymer chemistry Materials Chemistry Copolymer Nuclear chemistry |
| Zdroj: | Journal of Applied Polymer Science. 94:1752-1758 |
| ISSN: | 0021-8995 |
| DOI: | 10.1002/app.21101 |
| Popis: | We developed a simple method for the deposition of a uniform layer of polyaniline (PANI) on the surface of acrylonitrile–butadiene–styrene (ABS). The method consisted of two steps: the soaking of ABS samples in a water-based aniline solution stabilized by surfactants followed by the oxidative polymerization of the adsorbed and absorbed monomer. The three types of surfactants (molecular N,N-dimethyl-octalamine-N-oxide, anionic sodium dodecyl sulfate, and cationic hexadecyl trimethyl ammonium bromide) were used to prepare and stabilize the aniline emulsions in water. After treatment, the ABS surface was completely covered by PANI (as seen with scanning electron microscopy). The surface conductivity after PANI coating reached values between 10−3 and 10−4 S/□ in the best developed conditions. The chemical nature of the surfactant affected the particular setting of the aniline/surfactant emulsion preparation (time of ultrasonification = 15–30 min), its optimal concentration (2–10 wt % aniline and 0.1–0.2M surfactant), and other parameters of treatment, such as time (10 s to 20 min) and temperature (20–60°C) of soaking. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1752–1758, 2004 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text