Intercalation of the layered solid acid HCa2Nb3O10 by organic amines
| Autor: | Allan J. Jacobson, Joseph T. Lewandowski, Jack W. Johnson |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
chemistry.chemical_classification
Materials science Organic base Mechanical Engineering Intercalation (chemistry) Inorganic chemistry Crystal structure Condensed Matter Physics chemistry.chemical_compound Crystallography Tetragonal crystal system Lattice constant chemistry Mechanics of Materials Pyridine X-ray crystallography General Materials Science Inorganic compound |
| Zdroj: | Materials Research Bulletin. 22:45-51 |
| ISSN: | 0025-5408 |
| DOI: | 10.1016/0025-5408(87)90148-6 |
| Popis: | Layered compounds of formula C/sub n/H/sub 2n+1/NH/sub 3/Ca/sub 2/Nb/sub 3/O/sub 10/ are formed by reaction of n-alkylamines with the solid acid HCa/sub 2/Nb/sub 3/O/sub 10/. Other organic bases such as pyridine can also be intercalated. The lattice constants of the new compounds have been determined by powder X-ray diffraction. The unit cells are tetragonal with a axes that are unchanged with variation of the intercalated amine. The c axes lengths (layer spacings) vary systematically with the hydrocarbon chain length of the alkylamine. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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