ChemInform Abstract: Electrophilic Substitution of Methylene-Bridged Polycyclic Aromatic Hydrocarbons
Autor: | Ronald G. Harvey, Elias Abu-Shqara, Cheng Xi Yang |
---|---|
Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 23 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.199245082 |
Popis: | The electrophilic bromination and formylation of the methylene-bridged polycyclic aromatic hydrocarbons 11H-benz[bc]aceanthrylene (2), 4H-cyclopenta[def]chrysene (3), 13H-dibenz[bc,l]aceanthrylene (4), and 4H-benzo[b]cyclopenta[mno]chrysene (5) were investigated. All reactions proceeded with high regioselectivity to afford predominantly a single major isomeric product. The sole exception was bromination of 3 which gave a small amount of a second isomeric product |
Databáze: | OpenAIRE |
Externí odkaz: |