Anodic dissolution of a metal accompanied by the formation of unstable anionic complexes

Autor:	Andrew V. Noskov, S. A. Lilin
Rok vydání:	2009
Předmět:	Component (thermodynamics) Chemistry Cut off value Organic Chemistry Inorganic chemistry Metals and Alloys Decomposition Surfaces Coatings and Films Diffusion layer Stability constants of complexes Chemical physics Metallic materials Materials Chemistry Anodic dissolution Electric potential
Zdroj:	Protection of Metals and Physical Chemistry of Surfaces. 45:746-751
ISSN:	2070-206X 2070-2051
DOI:	10.1134/s2070205109060185
Popis:	Transport processes that take place during the anodic dissolution of a metal accompanied by the formation of negatively charged intermediate particles are theoretically considered. Distributions of the component concentrations and electric potential in the diffusion layer during the quasi-equilibrium decomposition of intermediate particles are calculated. Analysis predicts the existence of the admissible concentration limit of anions depending on the stability constant of intermediate particles. The effect of the stability constant on the potential distribution within the diffusion layer and on the shape of voltammetric curves of the process is found to be complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::641f0dc999fc022085127aef56943d79 https://doi.org/10.1134/s2070205109060185 Zobrazit plný text záznamu Plný text ve formátu PDF