Synthesis and spectral luminescent characteristics of the porphyrin complexes with the platinum group metals
Autor: | A. F. Mironov, N. P. Ivanovskaya, S. V. Tsukanov, N. S. Osin, V. D. Rumyantseva, L. I. Konovalenko |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Russian Journal of Bioorganic Chemistry. 34:239-244 |
ISSN: | 1573-9163 1068-1620 |
DOI: | 10.1134/s1068162008020155 |
Popis: | The syntheses of complexes of natural and synthetic porphyrins with Pt, Pd, Rh, and Ru are reported. Their electronic absorption spectra, phosphorescence spectra, and lifetimes at room temperature both in the presence and in the absence of oxygen were studied. Variations in the nature of the central metal atom and in the substituents in pyrrol and phenyl rings allow the obtaining of metalloporphyrins phosphorescing at room temperature with various phosphorescence excitation and emission spectra. |
Databáze: | OpenAIRE |
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