Synthesis and spectral luminescent characteristics of the porphyrin complexes with the platinum group metals

Autor: A. F. Mironov, N. P. Ivanovskaya, S. V. Tsukanov, N. S. Osin, V. D. Rumyantseva, L. I. Konovalenko
Rok vydání: 2008
Předmět:
Zdroj: Russian Journal of Bioorganic Chemistry. 34:239-244
ISSN: 1573-9163
1068-1620
DOI: 10.1134/s1068162008020155
Popis: The syntheses of complexes of natural and synthetic porphyrins with Pt, Pd, Rh, and Ru are reported. Their electronic absorption spectra, phosphorescence spectra, and lifetimes at room temperature both in the presence and in the absence of oxygen were studied. Variations in the nature of the central metal atom and in the substituents in pyrrol and phenyl rings allow the obtaining of metalloporphyrins phosphorescing at room temperature with various phosphorescence excitation and emission spectra.
Databáze: OpenAIRE