DPDS–DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism

Autor:	Roberto Cortés, Gotzon Madariaga, Jose Maria Ezpeleta, Ana B. Caballero, Juan M. Salas, Antonio Rodríguez-Diéguez, Noelia De la Pinta
Rok vydání:	2014
Předmět:	chemistry.chemical_classification In situ Nucleophilic addition Ligand Metallurgy General Chemistry Condensed Matter Physics Coordination complex Metal chemistry visual_art Polymer chemistry visual_art.visual_art_medium General Materials Science
Zdroj:	CrystEngComm. 16:8322-8326
ISSN:	1466-8033
DOI:	10.1039/c4ce00781f
Popis:	A cleavage–reorganization reaction at room temperature has been detected in three metal organic coordination compounds synthesized from a DPDS [di(4-pyridyl)disulphide] ligand: Mn(NCS)2(DPS)4 (1), [Fe(NCS)2(DPS)2]·2H2O (2) and Zn(NCO)2(DPS) (3), [DPS = di(4-pyridyl)sulphide].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::63f3e97327496b2a90f25e9f7003ccbe https://doi.org/10.1039/c4ce00781f Zobrazit plný text záznamu