Dismutierungsreaktionen der trifluormethyl(halogen)stannane, (CF3)nSnX4 − n (X = Cl, Br, I)
| Autor: | R. Eujen, N. Jahn |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
Trifluoromethyl
Organic Chemistry Inorganic chemistry Halogenation Infrared spectroscopy Halide Nuclear magnetic resonance spectroscopy Biochemistry Stannane Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound symbols.namesake chemistry Yield (chemistry) symbols Environmental Chemistry Physical and Theoretical Chemistry Raman spectroscopy |
| Zdroj: | Journal of Fluorine Chemistry. 71:75-79 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/0022-1139(94)03156-t |
| Popis: | Trifluoromethyl/halide exchange has been studied for (CF3)nSnX4 − n (n = 1, 2; X = Cl, Br, I) by 19F NMR spectroscopy at elevated temperature and has been utilized for an improved synthesis of (CF3)2SnBr2. The otherwise not readily accessible (CF3)3SnBr has been obtained in high yield from (CF3)4Sn and tetrakis(p-tolyl)stannane, followed by low-temperature bromination. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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