Synthesis and Characterization of Oxozirconium(IV) Aryloxides

Autor:	Champa Verma, Neeraj Sharma, S. S. Bhatt, Subhash C. Chaudhry
Rok vydání:	2007
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Inorganic chemistry Zirconyl chloride Proton NMR Anhydrous Phenols Physical and Theoretical Chemistry Triethylamine Nuclear chemistry
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 37:249-253
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533170701316494
Popis:	Oxozirconium(IV) aryloxides of the composition ZrO(OAr)2 and ZrOCl(OAr) (where OAr=OC6H4Cl‐2 and OC6H4NO2‐4) have been synthesized by reacting anhydrous zirconyl chloride with the respective phenols in the presence of triethylamine in predetermined molar ratios. The double aryloxides of the composition Na2[ZrO(OAr)4] have also been synthesized by reacting ZrO(OAr)2 with a bimolar amount of the corresponding NaOAr. The complexes have been characterized by elemental analyses, conductance, cryoscopy, IR and 1H NMR studies. The thermal behavior of the compounds has been explored and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::63c11b20a2f4c291dc51c9aa4074bd23 https://doi.org/10.1080/15533170701316494 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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