Green propene through the selective hydrogenolysis of glycerol over supported iron-molybdenum catalyst: The original history
| Autor: | Jhon E. Mellizo, Ana Maria Rocco, José Carlos Souza Fadigas, Rossano Gambetta, Valter L.C. Gonçalves, Claudio J. A. Mota |
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| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Process Chemistry and Technology Inorganic chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Propene chemistry.chemical_compound chemistry Hydrogenolysis Propane Molybdenum medicine Glycerol Physical and Theoretical Chemistry Selectivity Activated carbon medicine.drug |
| Zdroj: | Journal of Molecular Catalysis A: Chemical. 422:158-164 |
| ISSN: | 1381-1169 |
| DOI: | 10.1016/j.molcata.2015.11.014 |
| Popis: | The hydrogenolysis of glycerol, a byproduct of biodiesel production, to propene was studied over supported metallic catalysts. About 100% glycerol conversion was observed for all catalysts, but the selectivity was dependent on the composition. Ru and Pd on activated carbon produced mainly propane and methane/ethane, respectively. Ni/Mo on activated carbon gave mainly propane, whereas Zn/Mo and Cu/Mo supported on activated carbon produced intermediate oxygenated compounds. Fe/Mo over activated carbon presented up to 90% selectivity to propene. This results may be explained in terms of the poor reductibility of the Fe/Mo catalysts, as shown by TPR and XRD experiments. A possible pathway from glycerol to propene involves the formation of acetol, 1,2-propanediol and 2-propanol as intermediates. |
| Databáze: | OpenAIRE |
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